Microstructural Assessment of Lime Consumption Rate and Pozzolanic Reaction Progress of a Lime-Stabilized Dispersive Soil

Author
Bu-Ali Sina University, Faculty of Eng., Civil Eng. Department, Iran
Abstract
The existence of soft clay and dispersive soft clay at the site of engineering structures is regarded as one of the geotechnical problems. This study is performed on silty soft clay that according to the experimental results showed 100% dispersivity potential. Due to the low bearing capacity of this type of soil in the site, the slaked lime was used to stabilize the soil geotechnical properties, to increase its strength, to decrease plasticity behaviour of soil, and to overcome its dispersive properties. The main goal of the present study is to determine the growth rate and progress of lime-soil pozzolanic reactions in short and long terms from micro- and macro- structural point of view, as well as the measurement of the consumed lime rate over the time and its effect on mechanical parameters of the stabilized soil. The results of this study allow determining the minimum percentage of the lime that is necessary to react with clay minerals for making an acceptable change in long-term properties of stabilized soil. In this regard, a number of tests carried out with different percentages (0 to 10 percent) of hydrated lime. The pH, electric conductivity (EC), unconfined compressive strength, and lime consumption rate determination by X-ray diffraction analysis were the tests used in this study to observe the progress of lime reaction with clay. In order to determine the microstructural and mineralogical changes, and reaction products formed in the modified soil, X-ray diffraction (XRD) evaluation and scanning electron microscopy images have been used. Among the most important results of the present study, this paper propose a simple criterion for the onset of pozzolanic reactions and determination of the consumed lime rate during the pozzolanic reaction process based on pH and electric conductivity measurements. Based on the results from pH, EC, XRD, and unconfined compressive strength (UCS) tests, the pozzolanic reaction occurs at EC ≥ 4 mS/cm. Following that, the formation of new components such as calcium silicate hydrate (CSH) and calcium aluminate hydrate (CAH) causes an increase in soil strength. Over the time, with the reduction of EC ≤ 4 mS/cm and pH ≤ 12.4, the progress rate of pozzolanic reaction and the progress rate in soil strength suspend. The results show that for the dispersive soil around 3-4% lime is sufficient for its short-term reaction, which includes cation exchange. Based on the achieved results, the use of 6% lime for stabilization of sample gives EC ≥ 4.0 mS/cm and pH ≥ 12 after the first 14 days period. The unconfined compressive strength of the stabilized sample increased around 10 times in the same period, while only 5% increase in strength observed after 14 days (EC ≤ 4.0 mS/cm and pH ≤ 12).

Keywords


[1] Ouhadi, V. R. & Goodarzi, R. V. "Assessment of the stability of a dispersive soil treated by alum", Engineering Geology, 2006. Vol. 85: 91-101.
[2] Al-Rawas, A.A. Hago, A.W., Al-Sarmi, H,. "Effect of lime, cement and Sarooj (artificial pozzolan) on the swelling potential of an expansive soil from Oman", Building and Environment, 2005, 40 (5), 681–687.
[3] Al-Mukhtar, M, Lasledj, A., Alcover, J., "Behaviour and mineralogy changes in lime-treated expansive soil at 20 °C", Applied Clay Science 2010. Vol, 50, 191–198.
[4] Mitchell, I. V.,"Pillared Layered Structures: Current Trends and Applications", 2005. Elsevier Applied Science.
[5] Yong, R. N., Sethi, A. J., Ludwig, H. P. & Jorgensen, M. A., "Physical chemistry of dispersive clay particle interaction", American Society of Civil Engineers, Chicago, 1978, 1-21.
[6] Sherard, J. I., Dunnigan, L. P. & Decher, R. S., "Some engineering problems with dispersive soils", ASTM, STP, 1977, No. 623: 3-12.
[7] Sherard, J. I., Dunnigan, L. P. & Decher, R. S., "Identification and nature of dispersive soil", Journal of Geotechnical Engineering Division, 1976, Vol. 102: 287-301.;
[8] Yong, R. N. & Warkentin, B. P., "Soil properties and behaviour",. Elsevier Scientific Publishing Company, 1975.
[9] Thompson, M. R. "Shear strength and elastic properties of lime-soil mixtures.", Highway Research Record, Washington, D.C., 1966, 139, 1-14.
[10] Basma, A.A., Tuncer, E.R., "Effect of lime on volume change and compressibility of expansive clays", Transportation Research Record, 1991, 1295, 52–61.
[11] Mallela, J., Quintus, H. V., and Smith, K. "Consideration of lime-stabilized layers in mechanistic-empirical pavement design", The National Lime Association, 2004.
[12] Alper, S., Gozde, I., Recep, Y.H., Kambiz, R., "Utilisation of a very high lime fly ash for improvement of Izmir clay", Building and Environment, 2006, 42 (2), 150–155.
[13] Eades, J.L., Grim, R.E., "A quick test to determine lime requirements for soil stabilization", Highway Research Record, 1966, 139, 61–72.
[14] Basma A.A., Tuncer E.R. "Effect of lime on volume change and compressibility of expansive clays", Transportation research record, 1992, 1295, 52-61.
[15] Afès, M., Didier, G., "Stabilization of expansive soils: the case of clay in the area of Mila (Algeria)", Bulletin of Engineering Geological Environment, 2000, 59 (1), 75–83.
[16] American Society for Testing and Materials,. ASTM, American Society for Testing, 1984.
[17] EPA,. "Process design manual, land application of municipal sludge, Municipal Environmental Research Laboratory", EPA-625/1-83-016, U.S. Government Printing Offices, New York, 1983.
Materials, ASTM, Annual Book of ASTM Standards, P.A., 1992. Philadelphia V.4, 08.
[18] Eltantawy and Arnold, I.N. Eltantawy and Arnold, P.W., "Reappraisal of ethylene glycol mono-ethyl ether (EGME) method for surface area estimation of clays", Soil Sci, 1973, 24, pp. 232–238.
[19] Handershot, W. H., and Duquette, M., "A simple barium chloride method for determining cation exchange capacity and exchangeable cations", Soil Sci. Soc. Am. J. 1986, 50, pp. 605–608.
[20] Ouhadi. V.R., Yong. R.N., "Experimental and theoretical evaluation of impact of clay microstructure on the quantitative mineral evaluation by XRD analysis", Elsevier Appl. Clay Sci. J. 2003, 23. pp 141-148.
[21] Ouhadi, V.R., "Study of transformation of clay minerals in the interaction process with additives by use of scanning electron microsope and XRD and its relation to mechanical behaviour", Iran. J. Crystallogr. Mineral. 2002, 10 (1), 87–97.
[22] Al-Mukhtar, M, Lasledj, A., Alcover, Behaviour and mineralogy changes in lime-treated expansive soil at 20 °C, Applied Clay Science 50 (2010) 191–198.
[23] Al-Mukhtar, M, Lasledj, A., Alcover, J., Behaviour and mineralogy changes in lime-treated expansive soil at 20 °C, Applied Clay Science 50, 191–198.