Numerical analysis of electrokinetic soil remediation for Mercury removal

Author
student
Abstract
Electrokinetic soil remediation is a promising technology that can be used for insitu treatment of fine-grained soils. In this study the numerical analyses of electro kinetic process in soil is considered. Numerical model is formulated for simulating mercury transport under an electric field using one-dimensional convection-diffusion equation that describes contaminant transport. The presented model is used for demonstrating the pH changes and mercury removal from kaolinite clay at last day. The finite difference method is used for solving the model. Computational programs were written in two ways of FTCS and Crank-Nicolson using MATLAB software. The Crank-Nicolson scheme has been more consistent with experimental results. Experimental results are used for the calibration of the model. The proposed numerical model shows good agreement with experimental results.

Keywords


  1. EPA, 1997. “Recent Development for In-Situ Treatment of Metal Contaminated Soils.

  2. Hunter, R.J. 1981. “Zeta Potential in Colloid Science”. Academic Press. London.

  3. Hamed, J., and Acar, Y. B., 1991. ‘‘Pb (II) Removal from Kaolinite by Electrokinetics’’ J. Geotech. Eng., Vol. 117, No. 2, pp. 241–271.

  4. Reddy, K. R., Chaparro, C., and Saichek, R. E., 2003. “Iodide-Enhanced Electrokinetic Remediation of Mercury-Contaminated Soils”, Journal of Environmental Engineering, 129(12), pp1137-1148.

  5. Reddy K.R. Darko-Kagya K. and AL.Hamdan A. 2011 Electrokinetic remediation of chlorinated aromatic and nitroaromatic organic contaminant in clay soil,Enviromental engineering science,28(6),pp405-413.

  6. Alshawabkeh, A. N., Acar, Y. B., (1992), “Removal of contaminants from soils by electrokinetics: A theoretical tretreatise ”, Environmental science and health, A 27, pp. 1835-1861

  7. Park J.S., Kim S.O., Kim K. W., Kim B. R., Moon S.H., ( 2003) “Numerical analysis for electrokinetic soil processing enhanced by chemical conditioning of the electrode reservoirs”,  Journal of Hazardous Materials,  B99 , pp.71–88.

  8.  Kim, S. O., Kim, J. J., Kim, K. W., Yun, S. T., 2003. “ models and Experiments on electrokinetic removal of Pb (II) from kaolinite clay ”, Separation science and technology, vol. 39, No. 8, pp. 1927-195.

  9. Ribeiro A.b. Rodrigues-Maroto J.M. Mateus E.P. and Gomes H. 2005 Removal of organic contamints from soils by an electrokinetic process : the case of atrazine experimental and modeling, Chemosphere ,59pp,1229-1239

  10. Kim, S. O., Kim, J. J., Yun, S. T., Kim, K. W., (2003), “ Numerical an experimental studies on Cadmium (II) transport in kaolinite clay under electrical fields”, water, air and soil pollution, vol. 150, pp. 135-162.

  11.  Alshavabkeh, A. N., (2001), “Basics and application of electrokinetic remediation”, handouts prepared for a short course, federal university of Rio de Janerio.

  12. Alshawabkeh, A. N. and Acar, Y. B., (1996), “ Electrokinetic remediation II: Theoretical model ”, journal of Geotechnical Engineering, Vol. 122, No. 3, pp. 186-196.

  13. Eykholt, G. R., 1992. ‘‘Driving and complicating features of the electrokinetic treatment of contaminated soils’’,  PhD thesis, Dept. of Civ. Engrg., Univ. of  Texas at Austin, Tex.

  14. Ahmad, H., (2005), “Evaluation and enhansment of electrokinetic technology for remediation of Chromium Copper Arsenic from clayey soil ”, PhD thesis, Dept. of Civil and environmental Eng., at Florida state university.

  15. Alshawabkeh, A. N., Yeung, A. T., Bricka, M. R., (1999). “practical aspects of in-situ electrokinetic extraction”, Environmental Engineering, vol. 125, No. 1, pp. 27-35.

  16. Alshawabkeh, A. N., (1994), “Theoretical and Experimental Modeling of Removing Contaminants from Soils by an Electric Field”,Ph.D. Thesis, Department of Civil and Environmental Engineering, The Louisiana State University.

  17. Lee, H. H., and Yang, J. W., 2000. “A New Method to Control Electrolytes pH by Circulation System in Electrokinetic Soil Remediation”, Journal of Hazardous Material, B77, pp. 277-240.

  18. کیایی، آ.، 1385. " پالایش خاکهای آلوده به جیوه به روش الکتروکینتیک پیشرفته"، پایان نامه کارشناسی ارشد، مهندسی عمران-محیط زیست، دانشکده عمران، دانشگاه تربیت مدرس

  19. Al-Hamdan, A. Z., Reddy, K. R., (2008). “ Electrokinetic remediation modeling incorporating geochemical effects ”, Environmental Engineering, vol. 134, No. 1, pp. 91-105.